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Thus, the radical scavenging capacity of low-molecular-weight antioxidants in an intracellular environment is negligible compared to the ROS scavenging/converting capacity of antioxidant enzymes

Zhang J, Wang Y, Li G, Yu H, Xie X (2014) Down-Regulation of Nicotinamide N -methyltransferase Induces Apoptosis in Human Breast Cancer Cells via the Mitochondria-Mediated Pathway

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Analogous to a house with 36 holes in the roof, you can imagine that you dont need to fix them all, before you start to see benefits