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10.1371/journal.pone.0009009 255 LavebrattC.YangL

Zoroglu et al 59 reported increased thiobarbituric acid reactive species levels in the serum of autistic patients

But its only a temporary shift

Psychiatry 17, 174186

One study in elderly insomniacs provided a tryptophan-enriched cereal bar in the late evening and found significant improvements in sleep (longer sleep time, fewer awakenings) along with increased melatonin and serotonin metabolite levels in urine