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Because free radical damage is at the heart of all cellular ageing and chronic disease, insufficient glutathione can be connected with all kinds of ill-health

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demonstrated that GSSH efflux occurs proximal upstream of NLRP3 inflammasome activation after exposure to DAMPs, the result being ROS accumulation and redox imbalance, which collectively trigger inflammasome activation

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Practically, this means that toxicity packages for MSN-phenolic systems should include matched non-malignant controls, hemocompatibility, macrophage and endothelial stress readouts, organ-level biodistribution, and time-resolved oxidative injury markers rather than relying only on acute viability assays

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