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While these shifts in the GSH/GSSG balance are essential for redox signaling and the maintenance of cellular metabolism and homeostatic function, sustained disequilibrium from excess GSSG formation ultimately increases protein mixed disulfide formation

Pentose phosphate pathway alterations in multi-drug resistant leukemic T-cells 31P NMR and enzymatic studies

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Soula et al., 2020)

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More recently, using Magnetic Resonance Spectroscopy Imaging, it was demonstrated that hyperpolarized 13 C-labeled DHA is rapidly taken up by cancer cells and converted to vitamin C, illustrating the tumors' reducing state 4