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Box 1: A Few General Kinetic Considerations for Studying ThiolDisulfide Interchange Reactions

for example, direct fluorination of 11-boronate ester 4a using copper-mediated fluorination with ( t BuCN) 2 CuOTf or Cu(OTf) 2 py 4 failed 68,69 , so did an indirect sequence of stannylationfluorination 70