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Funding This research was funded by the National Natural Science Foundation of China (grant no

Furthermore, the primary isotope effect on the reaction kinetics was observed, which suggests the deprotonation of the -proton of hemithioacetal is the rate-determining step (Supplementary Fig

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605,606 Studies further indicate hydroxytyrosol, which is highly concentrated in extra virgin olive oil, may counteract endothelial dysfunction not only by reducing oxidative stress and inflammation, but also vascular aging and stiffness